The Henry H. Hill collection consists of historical and genealogical research compiled by Hill during his lifetime in southwest Virginia. Research includes Hill biographical information (1941-1950), Blacksburg history and Montgomery County (1798-1951, n.d.), Virginia Polytechnic Institute (VPI; 1891-1952, n.d.), American Civil War history (1863-1963, n.d.), and genealogical information and biographical sketches (1821-1950, n.d.). These materials comprise almost exclusively of photocopies and typescripts, so the dates reflected above are from the original source of the typescript and not the actual dates of the material. The dates of the material are included in the contents list.

Additionally, glass plate negatives and film negatives depict VPI campus views, cadet life, individuals, art works, and VPI footballs players, teams, and events.